I am not a chemist and am not in the hot tub business in any way. I had an Optima for a number of years and recently purchased an Artesian tub. So take these comments any way you like. I believe you are not using an adequate method of sanitation, and you are not adequately removing the metals from your water. I believe the SpaGuard stain and scale product is more for calcium scale control than to remove metals. You need to use Leisure Time Metal Gon. As soon as you fill the tub, pour in a whole bottle around the edges of the tub. Put in nothing else. Run the pumps and filter the water. The iron and other metals will get caught in the filter. If you have lots of iron, the filter will turn an orangish color. Keep rinsing the filter until the metals are gone. In bad cases of well water (like mine), this can take a day or two. If your water is clear when you fill the tub (rather than brown or green), use the Metal Gon, but then you probably do not need to wait to do the rest. Nature2 is great, but in most cases will not work by itself. You really need to use a clorine (dichlor) or bromine system. Clorine involves putting some in after each use and weekly shocks. Bromine involves using granular bromine when filling the tub and bromine tabs in a floater thereafter, and weekly shocks. The RHTubs website, under faq, has a couple of detailed clorine procedures. There is also some good bromine information. Nature2 should allow you to use less clorine or bromine, but it will not work alone just with weekly shocks. I tried it once just as Nature2 says with MPS (a nonclorine shock) added before each use. It did not work. The water always turned bad. To be fair, my tub had alot of use at the time. I use a bromine system with ozone and a frog mineral stick (Nature2 cannot be used with bromine). It is easy once you learn it. Lots of people like and use a clorine system. I think the real difference is whether having to put chemicals in after each use works for you. Hope this helps. Jeff