Hey Spaguy, just got the test results from the Pool store, also Vitamin C does not work on these stains, tried multiple time rubbing the vitamin onto the stain, it doesn't even lighten up. (also tried Chlorine Puck over stain nothing, and even these pouches they sell at pool store for stains and no result)
Free Chlorine 0.33
Total Chlorine 2.06
Combined Chlorine 1.73
PH 8.1
Hardness 202
Alkalinity 121
Cyanuric 8
Copper 0.2
Iron 0.1
Also pool heater is on alot, wife like water hot, so must be metal staining, these stains are all from last year when I wasn't using a metal sequestor every 2 weeks. (since then no new stains)