New member here, but I wanted to add a data point to the ozone+chlorine question.
Recently I bought a new 2010 spa with an ozonator. My intent was to use the dichlor/bleach method. For the first few weeks, with light use, everything seemed fine, although I did notice that the chlorine demand was somewhat high, >50%. After my kids had a hot tub party, I had a hard time getting the CC down, but since it had been about a month since the initial fill, I figured it was time to drain and refill anyway. I first did a 45 minute bleach decontamination to ~100ppm Cl, drained, then refilled, which left about 10 ppm. In 12 hours, there was no Cl. I figured that was because there was no CYA. I shocked up to 13 ppm with dichlor. That disappeared in 12 hours too. Suspecting the ozone was eating the Cl, I unplugged the ozonator and shocked to 13 ppm with dichlor. Voila! 12 hours later, the FC was 11 and continued to disappear at the rate of about 33%/day. With the ozonator off, I have not had any problem maintaining the chlorine level.
So, my empiric test confirms QCD's explanation. I don't know if the Cl would be more compatible with ozone now that I have more CYA in the tub. I've now added a total of 3 oz of dichlor to the 500 gallon tub, so I should have 20-30 ppm CYA by now. When I bought the tub, I thought the ozonator was a great idea. Now, I'm not convinced. By adding another reaction to the chemistry, it would seem to make the Cl levels less predictable.
Any thoughts?