Thank you all. I think that Dlleno is right that the high CYA levels may have been inhibiting the bromine.
I'm a bit confused about the statement "your chlorine is what generates the bromine from bromide...", as I'm not using chlorine. I take it that there is chlorine in the 2-in-1 bromine sanitizer? The bottle says 14.7% sodium bromide and 82.5% sodium dichloro-s-triazinetrione. Is the latter one a chlorine I'm guessing?
I take it that shocking with this sanitizer may be adding too much bromine, too much CYA, and not reactiving the existing bromine?
Anyways, I've drained and started from scratch. The bad fumes I was having are gone, and I was surprised to see how little bromide it took to bring the levels to their ideal - much less than it was taking previously, which I think again supports the idea that maybe the CYA was inhibiting something.
What is your ideal method for bromine treatment? Should I use this sanitizer mix, or is it better to have them separate so I can shock with a non-chlorine oxidizer and then see what the levels look like before adding additional bromine? Should I use a float or is it better to only add as needed or after use? I'd love to hear your process and exactly what chemicals you use!